Well a cooling system only runs at 13-18psi when warm, 0 psi when cold, and a cylinder has 150psi compression and 600+psi when it fires.
So a blown head gasket(or cracked head) usually allows this higher pressure into the cooling system which forces out coolant(into overflow tank) and creates an "air" bubble in the head causing overheating.
You can take off the rad cap on a cold engine, coolant should be right at the top, no air gap; and then start the engine, watch the coolant in the rad cap opening, none should come out, i.e. bubble up and overflow, keep watching it for any bubbles, there should be none.
Two or three minutes is fine, shut off engine and put rad cap back on.
If coolant does overflow a bit or you do see some bubbles, then you could have a cold seal issue with the head gasket and that will just get worse over time.
This usually only comes up on bi-metal engines, aluminum head and cast iron block, aluminum's expansion and contraction rates are a lot different than cast iron, aluminum contracts faster when cooling, and with the 13-18psi in the warm cooling system and 0psi in the now shut off engine, it can leak into a cylinder.
When engine is restarted, the coolant in the cylinder is burn off(white smoke), and then this small leak is sealed by the rapidly expanding aluminum head, so no sign of a head gasket leak........for now.
I have not seen this on matching metal engines, i.e. aluminum/aluminum or cast iron/cast iron
White smoke when starting a cold engine can be normal depending on the local weather.
Burning gasoline creates water, this is why you see water drip out the tail pipe or why exhaust systems can rust from the inside out.
Local humidity also plays a roll in that the engine is sucking the humidity in along with the air to burn with the gas.
After turning off an engine the exhaust system cools and that moisture condenses inside the pipes, cats, and mufflers.
If local humidity is high it won't evaporate.
Next time you start the engine the 800+ deg exhaust gas vaporizes the condensed water in the exhaust system almost instantly which is the white smoke you see.
This should only last for a short time as the exhaust system gets completely heated up.
If there is coolant getting into the cylinder when engine sits you would smell it at startup, very distinctive smell, nothing like an exhaust smell.
Blackish smoke is more related to a rich mix, blueish is oil being burned.
I would pull a one spark plug from each cylinder and look at their tips, this will tell you if engine is running rich; and if a spark plug is super clean, like new, it would tell you that cylinder is getting coolant inside and steam cleaning the spark plug.
Google: images for spark plug condition
To see what the spark plug tips tell you