At least one of the water pump bolts is 'through' into the jacket, so likely needs some thread sealer. The red is thread locker residue, I think.
Cam sprocket torque seems reasonable to me. It is kinda hard to hold in position as I remember...
It makes sense to me to use a tap to clean the threads in the block fastener holes. There are 'cleaners'(thread chasers) available if you don't have a tap and die set. HF sells them for ~$20-ish, but beware of the sizes as sometimes you get two of something and none of something else.
I likely would put anti-seize on the exhaust bolts, if there was a chance I would be removing it in the future. Don't know how much it would do, but couldn't hurt to try. No other bolts need it as far as I can remember. Cam cover, intake, accessory mounts(alt, A/C, PS, nothing special)
tom