I always left mine alone. The only reason I know what it looks like when you drain it is when I drained it for other work or to fix the original problem.
Occasionally it did not work. When it didn't work, the coolant would spray all over the engine compartment (it was a big leak that it did not fix) and it left a white residue all over everything. What a mess. But it's worth the risk if it stops the leak.
Some people's life situations are different, and a can of stop leak can keep from making things in your life worse than they already are. Money or lack there of comes to mind as one of those life situations.
If you find yourself one day with a leak, and you are out in the middle of no where, what can help the situation also is to run with the radiator cap loose. Unless it's 100 degrees outside and you are towing or hauling something, 90% of the time you can run a engine with the cap loose and run zero pressure on the system. It won't boil over unless you get over 212 F. Or if you live in Denver, it will boil over at 203 F. The thermostats on most of these trucks is 190-195 F.