Which cylinder and was it one with a faulty injector?
Burnt valve means a hot spot in the cylinder.
Running too lean causes hot spots, so a faulty injector could do that.
Blocked cooling passage near that valve can cause a hot spot, hot tanking head will usually clean it out but could be a casting flaw if head is low miles, under 100k, probably not on an '86
The exhaust valve runs at a higher temp than the intake because intake is cooled by incoming fuel/air, so exhaust valve is most likely to get burnt but they are also made of stronger compounds.
The valve seat for each exhaust valve is very important, the valve seat is cooled by the coolant, the exhaust valve is then cooled by its contact with the seat, 75% of valve cooling is done by contact with the seat, if the valve and seat are not matched then full contact isn't possible, so full cooling isn't possible.
Valve defects are know issues, one replacement valve manufacturer, claimed 1 on 5 OEM valves could be defective, not sure it would be that high, lol, but I know it does happen.
Best thing you can do is to check all possible external reasons for that 1 valve to fail and if nothing can be found then "defective valve" is what you are left with.
I would check with a few local machine shops and get pricing on valve job + cleaning and surfacing, they can check and reseat valves not replace them all, although replacing all the exhaust valves might be a good idea.