Should be fine doing that
Good read here on the 4.6l Modular V8 engine:
http://www.curbsideclassic.com/blog/engine-history-the-ford-4-6-liter-v8/
The EVAP system is an "emissions" system, so a priority system, for the computer.
It basically consists of a charcoal canister, a solenoid and a pressure sensor.
After startup the computer opens the solenoid which applies Engine Vacuum to charcoal canister, the canister has a hose to the gas tank, tank should be sealed when non-vented gas cap is used.
The pressure sensor will show negative air pressure as vacuum is applied to the sealed tank/system
Computer stops applying vacuum and watches if negative pressure holds
If it does then EVAP system passes the test, and computer will apply vacuum on and off as you drive to keep gasoline fumes, from gas sloshing around in the tank, from polluting our air
If pressure doesn't hold then computer turns on CEL(check engine light) and sets EVAP code
1996 computer will expect a working EVAP system, you can use parts from the Crown Vic system, solenoid and pressure sensor for sure because wiring connectors will match up, but you can use a smaller charcoal canister from another vehicle if the Crown Vic's is too big and looks ugly, lol.
You also need to seal up the gas tank
Not sure if the 1996 Crown Vic will also have a Purge valve as part of EVAP system?