Sorry, it is more complicated than one simple answer.
A properly constructed exhaust system provides a range of pressure differentials, depending on the specific area and where it is in the combustion cycle.
Too low a pressure immediately post exhaust valve will draw a portion of the intake charge out of the cylinder.
This is why they run pipes on high end drag cars.
This is also why good headers are designed or tuned to take advantage of the various exhaust pulses.
On the other hand, Frank is correct in saying that a well designed exhaust will create negative pressure in the downline to scavenge the exhaust that has left the runners, although too much will effect the upper end, lowering torque and efficiency.
However, he is wrong when he says that cats don't do anything. They are necessary to cut down on engine emissions, which effect the air that we all breathe.
Its about time that people woke up to the fact that if you drive, you have a responsibility to keep your junk running right, and not polluting any more than necessary. If you've got an oil leak or your cooling system leaks, you need to get it fixed. The same for the cats.