Those numbers are very low, could just be your gauge and if so you may be wasting money on a rebuild at this time.
Generally gasoline engine compression in psi will be 18.3 x Compression ratio
so 5.0l with 9.0:1 compression ratio should be 18.3 x 9 = 164.7psi
That's at sea level air pressure, might be 155psi at 8,000ft
And this is with cold engine.
Actual 100psi on a V8 engine might start but it would be iffy, so the slow to start would fit with low compression.
The 100-90psi spread is 10% so not unusual, 65psi could be a glitch so.............
I would retest
Remove ALL spark plugs for the test, you need good crank shaft speed to get accurate PSI numbers.
Push gas pedal to the floor when cranking engine, this turns off fuel injectors and also allows for good air flow.
Compression gauge needs at least 4 "hits" of that cylinders compression stroke.
Write it down.
If gauge seems OK and numbers are still low then I would suspect timing chain since all cylinders are low, or rocker arm adjustment, yes rings do wear out but those numbers are really too low for bad rings.
If you want to test for ring problems then do the "dry" compression test as above.
Then repeat and add a teaspoon of oil via spark plug hole before testing a cylinder, a "wet" test, the oil will help seal bad rings and compression will jump up 30psi, if only a 10psi or less increase then rings are fine.
Take a straw, drip it in a can/bottle of oil and put your finger over the end of the straw, pull out the straw, put it on a teaspoon and let finger off the end.
mark straw at teaspoon full level then use the straw to get the oil and put it in the cylinder.