There is some good suggestions above. I do the following checks when evaluating 4WD system before using 4WD.
1) With hubs unlocked, and it in 2WD, and all wheels on the ground, make sure the front shaft turns smooth. At least one of the front side shafts should also turn, but you can manually turn each side shaft to make sure they turn free (hubs unlocked). With it in 2WD and hubs unlocked nothing should be holding these shafts.
2) Put in 4WD (hubs unlocked still), the front drive shaft should not turn since it is now locked to the transmission/engine. Turning one side shaft should result in other side shaft turning in opposite direction since the side shafts are still free to turn in the hubs.
3) Return transfer case to 2WD and lock both hubs. The front drive shaft should not turn in this case either. While not connected to trans/engine it is connected to the wheels now so only should turn if the truck rolls. If it does turn, probably one of the side shafts is also turning and this is a sign that the hub on that side did not lock.
4) With both hubs locked, leaving it in 2WD, try driving on dry pavement. With it in 2WD it won't bind, but now you have the front drive shaft assembly spinning. One in good condition should be pretty smooth except for tight turns where there may be some click or feel in the wheel since there aren't CV joints at the wheels. There should generally be some extra rolling noise if you know how the truck normally sounds but it shouldn't be really loud. There shouldn't be any pings or heavy vibration associated with it. I've driven at highway speeds like that regularly. If it is pretty smooth, you got a good running front end system and are good to go with 4WD which you probably don't want to do on dry pavement.
I have one more check that I do on dry pavement to check the balance (all tires the same size) which is while moving strait at slow speed slip it into 4WD and make sure it remains smooth. Do not turn while doing this as it will bind. If it binds in 30 or 40 ft, you probably have un-matched tires. Return it back to 2WD.