Cooling system pressure
Water boils at 212degF at sea level, at 5,000ft elevation(Denver) it boils at 203degF, so it changes with elevation
Boiling point of 50/50 mix of anti-freeze and water is 223degF, at sea level, its the anti-freeze part, the ethylene glycol, that does this, it also lowers the freezing point of 50/50 mix to -35degF
But even at 223degF an engine might boil over pulling a load or on a long uphill grade
So back to the sea level/Denver thing, at sea level there is about 15lbs of air pressure, in Denver about 12lbs, so boiling point goes down when pressure goes down, about 3deg per pound, so what happens if pressure goes UP?
So cooling system is pressurized to raise the boiling point of 50/50 mix, you get about 3degF per Pound of pressure
So 15lbs cap would add 45degF to boiling point of 50/50 mix, 223 + 45 = 268degF boiling point, now thats more like it
If an engine gets above 250deg something is WRONG
You can go with higher pressure but then you risk blowing off hoses and or gaskets, and there is no real gain because if engine is getting hotter than 250degF there is a problem, that's about 3/4 on a temp gauge
12lb cap is OK on some engines, thats 36degF more so, 223 + 36 = 259degF
Cooling system GETS its pressure from the 50/50 mix expanding as its heated, like ALL liquids do, thats how a pressure cooker works.
So the pressure is "free", nothing else is needed but a sealed system and a pressure relief valve(rad cap)
Most vehicles use a 14 to 16psi cap, this is strictly for the boiling point of the liquid used in the system.
Now you do lose 10degF on boiling point of any liquid when driving at higher elevations so using a lower pressure cap in Denver might not be the best idea