ACs have a pressure control switch. If there's no refrigerant, it won't kick on. It's difficult to know what's going on refrigerant wise without specific tools. Fast, dirty, cheap and illegal way to check would be to unscrew the plastic cover for the charging/testing port (it should be close to the accumulator, a large black canister with A/C lines coming out of it, probably close to the heater core), then wearing heavy gloves use a small screwdriver to press in the little pin under that cap. All that pin is is a schraeder valve (like to fill your tires) but if your system has any charge left by quickly depressing that pin it will shoot out some of the freon. If nothing comes out then you have no charge, and thus probably also have a leak someplace. If you do get gas you might be either really low or have an electrical/control problem. It's not a sure thing either way but it's somewhat of a start.
Don't forget the gloves. It's unlikely to occur with just a bit of it but direct exposure to refrigerant will cause frostbite.
Edit: I am a slow typist....
I would have to agree with adsm08 though. This is a special tools kind of job, and everything you'll need is not cheap or useful for anything else (unless you do HVAC for a living, but I suspect you don't). Technically IIRC you should have an EPA 609 certification to touch this kind of stuff legally anyhow.